The third instalment of the teen vampire romance took £13 million, which beat Alice In Wonderland's £10 million debut from March.
Eclipse's sum also beat the last Twilight film, New Moon, which earned £11 million on its first weekend on release last year.
Shrek Forever After topples to second place, while the new Predators revamp shoots into number three.
Get Him To The Greek and Killers complete the top five.
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